Give the method of preparation of ethyne (acetylene) from vicinal dihalides.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Vicinal dihalides are compounds in which two halogen atoms are attached to adjacent carbon atoms.
When vicinal dihalides are treated with alcoholic potassium hydroxide $(KOH)$,they undergo dehydrohalogenation to form vinyl halides,which then react with sodamide $(NaNH_2)$ to form ethyne.
The reaction is as follows:
$CH_2Br-CH_2Br + 2KOH (\text{alc.}) \longrightarrow CH \equiv CH + 2KBr + 2H_2O$
Alternatively,using $NaNH_2$ in liquid ammonia:
$CH_2Br-CH_2Br \xrightarrow{NaNH_2 / liq. NH_3} CH \equiv CH$

Explore More

Similar Questions

Which one of the following classes of compounds is obtained by the cyclic polymerization of acetylene?

Which of the following bonds is the most reactive?

The product$(s)$ obtained via oxymercuration $(HgSO_4 + H_2SO_4)$ of $but-1-yne$ would be

$CH_3-CH(CH_3)-C \equiv CH \xrightarrow{excess \ HBr}$
The product of the above reaction is

An unknown compound $X$ is an unsaturated hydrocarbon. It reacts with $HgSO_4$ and $H_2SO_4$ to give compound $(B)$. Compound $(B)$ on oxidation gives compound $(C)$. Compound $(C)$ on reaction with $NaOH$ and soda lime gives methane. Identify $A$ (which is $X$),$B$,and $C$ by providing the chemical reactions.

Difficult
View Solution

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo